Modification of poly(styrene-b-(ethylene-co-butylene)-b-styrene) via free-radical grafting and its photo-crosslinking
Agnès Harlay
ICGM, University of Montpellier, CNRS, ENSCM, Montpellier, France
Polymers Composites and Hybrids (PCH), IMT Mines Ales, Ales, France
ARMOR, ZAC Le Taillis, Les Sorinères, France
Search for more papers by this authorThomas Brossier
ICGM, University of Montpellier, CNRS, ENSCM, Montpellier, France
Search for more papers by this authorMarcos Batistella
Polymers Composites and Hybrids (PCH), IMT Mines Ales, Ales, France
Search for more papers by this authorArnaud Regazzi
LMGC, IMT Mines Ales, University of Montpellier, CNRS, Ales, France
Search for more papers by this authorCorresponding Author
Sébastien Blanquer
ICGM, University of Montpellier, CNRS, ENSCM, Montpellier, France
Correspondence
Sébastien Blanquer, ICGM, University of Montpellier, CNRS, ENSCM, Building 17, Montpellier, 34095, France.
Email: [email protected]
Search for more papers by this authorJosé Lopez-Cuesta
Polymers Composites and Hybrids (PCH), IMT Mines Ales, Ales, France
Search for more papers by this authorJean-Jacques Robin
ICGM, University of Montpellier, CNRS, ENSCM, Montpellier, France
Search for more papers by this authorAgnès Harlay
ICGM, University of Montpellier, CNRS, ENSCM, Montpellier, France
Polymers Composites and Hybrids (PCH), IMT Mines Ales, Ales, France
ARMOR, ZAC Le Taillis, Les Sorinères, France
Search for more papers by this authorThomas Brossier
ICGM, University of Montpellier, CNRS, ENSCM, Montpellier, France
Search for more papers by this authorMarcos Batistella
Polymers Composites and Hybrids (PCH), IMT Mines Ales, Ales, France
Search for more papers by this authorArnaud Regazzi
LMGC, IMT Mines Ales, University of Montpellier, CNRS, Ales, France
Search for more papers by this authorCorresponding Author
Sébastien Blanquer
ICGM, University of Montpellier, CNRS, ENSCM, Montpellier, France
Correspondence
Sébastien Blanquer, ICGM, University of Montpellier, CNRS, ENSCM, Building 17, Montpellier, 34095, France.
Email: [email protected]
Search for more papers by this authorJosé Lopez-Cuesta
Polymers Composites and Hybrids (PCH), IMT Mines Ales, Ales, France
Search for more papers by this authorJean-Jacques Robin
ICGM, University of Montpellier, CNRS, ENSCM, Montpellier, France
Search for more papers by this authorFunding information: Association Nationale de la Recherche et de la Technologie
Abstract
Poly(styrene-b-(ethylene-co-butylene)-b-styrene) (SEBS) is functionalized via radical grafting with 4-vinyl-1-cyclohexene 1,2-epoxide (VCHO) initiated using 2,5-Bis(tert-butylperoxy)-2,5-dimethylhexane. The existence of the epoxide group on the SEBS backbone is evidenced by 1H nuclear magnetic resonance. A size exclusion chromatography (SEC) study reveals some chain coupling, and this phenomenon is limited by controlling the quantities of peroxide and monomer reagents used during the radical grafting. Photo-crosslinking of SEBS-g-VCHO under ultraviolet irradiation in the presence of a cationic initiator is then successfully performed with resultant gel contents higher than 85%. Mechanical properties of SEBS and crosslinked materials are measured by tensile tests on thin films. On the one hand, those tests reveal a significant increase of Young's modulus of the crosslinked materials. On the other hand, the diminution of elongation at break is much more limited; crosslinked materials retain their elastomeric properties with an elongation at break greater than 200%. Finally, the photosensitive SEBS-g-VCHO is used to show the adhesion performance of the photo-crosslinking coating as well as a resin for the stereolithography process.
Supporting Information
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